P. 595 Section Review
2. a. reduction b. oxidation c. oxidation d. reduction e. reduction f.
oxidation g. reduction h. reduction
3. a. redox b. redox c. not redox d. redox e. not redox
4. a. O-2 is oxidized to O2 ; N+5 is reduced to N+3
b. H2 is oxidized to O2 ; Cu2 is reduced to Cu
d. H2 is oxidized to H ; Cl2 is reduced to Cl
5. a. Three electrons are lost in the oxidation half-reaction; Three
electrons
are gained in the reduction process. The balanced equation has a charge
of 3+
on both sides.
b. There are 3 mol of Na and 1 mol o Al on both sides of the equation.
c. The number of electrons lost equals the number of electrons gained,
so
they cancel out in the overall equation.
6 a. yes, b. yes, c. no d.yes, e. no
Problems / Concepts P. 618
1. a. Oxidation causes atoms or ions to attain a more positive
oxidation state
and lose electrons. Reduction causes atoms or ions to attain a more
negative
oxidation state and gain electron.
b. Oxidation: Na--> Na+ + e-
Reduction: Cl2+2e- ? 2Cl-
2. a, b, c, f, g, I
3. Equation Oxidized Reduced
a Na Cl2
b C O2
c O-2 H+1
f O-2 Cl+5
g H2 Cl2
I Zn Cu2+
p. 618
12.
a. oxidation K --> K+ + e-
b. reduction: S + 2e- --> S 2-
c. oxidation: Mg -->Mg 2+ + 2e-
d. oxidation: 2F- -->F2 + 2e-
e. oxidation: H2 --> 2H+ + 2e-
f. reduction: O2 + 4e- --> 2O2-
g. reduction: Fe3+ + e- -->Fe2+
h. oxidation: Mn2+ -->MnO4- + 5e-
12. 13.
a. nonredox
b. redox
c. nonredox
15.
a. 0
H2
b. +1 2
H2O
c.
0
Al
d.
+2 2
MgO
e.
+3 2
Al2S3
f.
+1+5 2
HNO3
g.
+1+6 2
H2SO4
h.
+2 2+1
Ca(OH)3
i.
+2 +5-2
Fe(NO3)2
j.
0
O2
More problems: Chapter 19 p.618 #'s 2, 5a.b.c., 6a.b.c.,
12a.b.c.d.,15a.b.c.d.e., 19, 20, 22
2. a, b, c, f, g, i,
5.
a. strongest: Ca Weakest Cl-
b. strongest Al weakest br-
c. strongest na, weakest F-
6. a. yes
b. yes
c. no
12. a. oxidation:K ---> K+ + e-
b. reduction: S + 2e- --->S2-
c. oxidation: Mg ---> Mg2+ + 2e-
d. oxidation: 2F- ---> F2+ 2e-
15. a. 0
H2
b. +1 -2
H2O
c. 0
Al
d. +2 -2
MgO
e. +3 -2
Al2S3
19. a. 2Ag+ + Cu ---> 2Ag + Cu2+
b. Co2+ + Cd --> Co + Cd2+
c. 2Na + Ni2+ ---> 2 Na+ +Ni
d. Br2 + 2I- ---> 2Br- + I2
20. a. +0.46V
b. +0.12V
c. +2.45V
d. +0.53V
21. a. +0.53 v, b.-2.20 v, c. no change
22. Ni+2Ag+ ---> Ni2+2Ag
E^0 = 0.26V = 0.80 V = +1.06V
nickel dissolves, solid silver forms
27. a. spont. b, spont. c. not spont. d. spontaneous